Removal of Lead and Zinc from Industrial Waste water by Amla leaves Nano-bioadsorbent
Abstract
In the present research work, amla leaves (Phyllanthusemblica) were used for preparing nanobioadsorbent to remove heavy metals viz. Lead (Pb) and Zinc (Zn) present in wastewater. The major advantage of using amla leaves as bioadsorbent is its easy availability, abundance, low cost, biodegradable and eco-friendly nature. Prepared bioadsorbent was characterized by infrared spectroscopy (IR), SEM and BET techniques. Variation in the experimental conditions such as pH, adsorbent dosage, stirring speed and contact time, were analysed at 30oC by UV-visible spectrophotometer at wavelength 479nm for Pb and 597nm for Zn. The rate of adsorption was studied under different conditions, including pH (Britton Robinson Buffer range 2-12), adsorbent dose (0.5g-
2g), contact time (0-60 min) and metal ions initial concentration (25ppm-100ppm). The maximum percentage removal of Pb and Zn were 97.4 % and 99% respectively by keeping the optimum experimental conditions such as initial metal ion concentration of 25 ppm, pH 8, adsorbent dose 1.5g, contact time 60 min etc. Results also showed that the percentage uptake of Pb and Zn decreased
gradually as the concentration increased from 25 to 100 ppm. The adsorption data were well studied for adsorption isotherms and kinetic models and followed the first order kinetics and best fitted to langumir and frendulich adsorption isotherm.
References
A.K. De, Environmental chemistry. 4th edition new age international (P) limited publisher, New Delhi 2000, 175-201.
C.S. Rao, Environmental pollution control engineering revised 2nd edition new age international (P) limited publisher, New Delhi 2011, 55-57.
W. Wesley, Eckenfelder, Industrial water pollution control,2nd edition McGraw-hill book company, Singapore 1987,40-71.
P.K. Goyal, Water pollution 2nd edition new age international (P) limited publisher, New Delhi 2006,65.
Berrazoum, A., Marouf, R., Ouadjenia, F. and Schott, J. (2015) Bioadsorption of a Reactive Dye from Aqueous Solution by Municipal Solid Waste. Biotechnology Reports, 7, 44-50. https://doi.org/10.1016/j.btre.2015.04.005
Bernard, E., Jimoh, A. and Odigure, J.O. (2013) Heavy Metals Removal from Industrial Wastewater by Activated Carbon Prepared from Coconut Shell. Research Journal of Chemical Science, 3, 3-9.
S. Rajoriya and B. Kaur, “Adsorptive Removal of Zinc from Wastewater by Natural Biosorbents,” Int. J. Eng. Sci. Invent., Vol. 3, No. 6, pp.60-80, 2014.
S.T. Abbas, M. Mustafa Al-Faize and A.Z. Rah., J. Chem. Pharm. Res., 2013, 5, 250.
Y. Thakur, M. Kumar and S. Singh, Res. J Pharm. BiolChem. Sci., 2015, 6, 1717.
V. K. Gupta, D. Pathania, S. Sharma and P. Singh, J. Colloid Interface Sci., 2013,401, 125.
A. Roy, S. Chakraborty, S.P. Kundu, S.B. Majumder and B. Adhikari, A. Carbohydr. Polym., 2013,92,2118.
M. C. Menkiti, M.C. Aneke, P.M. Ejikeme, O.D. Onukwuliand and N.U. Menkiti, R. plus30, 2014, 203,213.
Y. Yang, Z. Wei, X. Zhang , X. Chen , D. Yue, Q. Yin , L. Xiao and L. Yang, Bioresour. Technol., 2014,171, 227.
J.H. Park , Y.S. Ok , S. H. Kim , J.S. Cho , J.S. Heo, R.D. Delaune and D.C. Seo, Chemosphere,2015,6535,580.
Mohite, B.V., Patil, S.V., 2014. Bacterial cellulose of Gluconoacetobacter hansenii as a potential bioadsorption agent for its green environment applications. J. Biomater. Sci. Polym. Ed. 25, 2053–2065.
M. Pereira, M.C. Bartolomé and S.S. Fortún,( Bioadsorption and bioaccumulation of chromium trivalent in Cr(III)-tolerant microalgae: A mechanisms for chromium resistance) Chemosphere.,2013, vol 6,1057.
J. Zhang, T. Ding, Z. Zhang, L. Xu and C. Zhang, treatment in two strains of Scenedesmus acutus M. (Chlorophyceae) with different chromium sensitivity PLoS One., 2015,10,1 .
S. Wang, M. Wei and Y. Huang, J. Agric. (Biosorption of Multifold Toxic Heavy Metal Ions from Aqueous Water onto Food Residue Eggshell Membrane Functionalized with Ammonium Thioglycolate) Food Chem., 2013,61, 4988. doi.org/10.1021/jf4003939
I Anastopoulos and G. Z. Kyzas, (Progress in batch biosorption of heavy metals onto algae) J. Mol. Liq.,2015, 209, 77. DOI: 10.1016/J.MOLLIQ.2015.05.023
T.L. Marques, V.N. Alves, L.M. Coelho and N.M. Coelho, Water. Sci. Technol., 201.65,1435.
J. Wang, S. C. Peng, Z.Q. Wan, Z.B. Yue, J. Wu and T.H. Chen, Bioresour Technol., 2013,132, 45345.
S. Sun , J. Yang ,Y. Li , K. Wang and X. Li , (Optimizing adsorption of Pb(II) by modified litchi pericarp using the response surface methodology) Ecotoxicol. Environ. Saf., 2014,108 29.
R. Jiang , J. Tian, H. Zheng, J. Qi , S. Sun and X. Li ,J Environ Manage., 2015,155,24.
Y. Feng , H. Zhou , G. Liu , J. Qiao, J. Wang , H. Lu , L. Yang and Y. Wu, Bioresour. Technol., 2012,125, 138.
M. A. Hossain, H.H. Ngo , W.S. Guo and T. Setiadi, Bioresour. Technol., 2012, 121, 386.
M. Bila, J.A. Shah, T. Ashfaq, S. M.Gardazi, A.A. Tahir, A. Pervez, H. Haroonand Q.M. Mahmood, J. Hazard. Mate., 2013,15,322.
H. Liu, Y. Dong, H. Wang and Y. Liu,( Effects of silica nanoparticles on growth and photosynthetic pigment contents of Scenedesmus obliquus) Volume 22, Issue 1 J. Environ. Sci., 2010, 22,155.
P. M. K. Reddy, S. Mahammadunnisa, B. Ramaraju, B. Sreedhar and C. Subrahmanyam, Environ. Sci. Pollut. Res., 2013, 20, 4111.
E. Bernard and A. (Heavy metals removal from industrial wastewater by activated carbon prepared from coconut shel) Jimoh, Intern.J. Engi. Appl. Sci., 2013, 4, 2.
S. Rajoriya and B. kaur, (Adsorptive Removal of Zinc from. Wastewater by Natural Biosorbents) Intern. J. of Eng. Sci. Inven. 2014, 3, 80.
M. Singanan, (Removal of lead (II) and cadmium (II) ions from wastewater using activated biocarbon) Science Asia, 2011,37, 119.
S.T. Ong, P.S. Keng, S.L. Lee, M.H. Leong, Y.T. Hung. Inter. J. Phys. Sci., 2010, 8,1276.
W. Rafeah, N. Zainab and U. Veronica, World Applied Sci J, 2009; 5, 91.
H. M. Zwain, Comprehensive Study on Wastewater Treatment Using Low Cost Adsorbent, LAP Lambert Academic Publishing, Saarbr¨ucken, Germany, 2012.
M.I. B. Toledo, J.R.R Utrilla, J.D. M. Díaz, M.S. Polo and F. C. Marín, J .Colloid. Interface. Sci., 2014,418,113.
F. L. Mi, S.J. Wu and F. M. Lin, (Adsorption of copper(II) ions by a chitosan–oxalate complex biosorbent) J. Biol. Macromol., 2015,72,136.
M.A. Hossain, H.H. Ngo , W.S. Guo and T.V. Nguyen, Bioresour. Technol., 2012,113, 97.
T. Altun and E. Pehlivan, (Removal of Cr (VI) from aqueous solutions by modified walnut shells) Food Chem., 2012,132, 693. DOI: 10.1016/j.foodchem.2011.10.099
J. L. Hu, X. W. He, C. R. Wang, J.W. Li and C. H. Zhang, Bioresour. Technol., 2012,121, 25.
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