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Inclusion of Gallium Oxide with Silver Oxide of Tunable Optical Properties for their Unusual Catalytic Performances

D. Nathiya, N.M.I. Alhaji, A. Ayeshamariam

Abstract


AgGaO2 nanocomposites were prepared by hydrothermal synthesis. The crystal was assessed using Scherer equation for the as-prepared nanoparticles and annealed samples of AgGaO2 at 40 and 55 nm, respectively. Silver and gallium nitrates were reacted in an alkaline medium using NaBH4, which was used to reduce particle size. The presence of relatively homogeneous nanocomposites was confirmed by X-ray diffraction. Morphological studies were analyzed by transmission and scanning electron microscopy. Vibration modes were produced by Fourier transforms infrared spectroscopy. Photocatalytic studies were performed for the as-prepared sample for three different dyes, namely, methylene blue, methyl orange and rhodamine-B. 

Keywords: AgGaO2, chemical synthesis, crystal size, dyes, frequency, photocatalytic degradation

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Benhaliliba M, Benouis CE, Aida MS, Ayeshamariam A. Fabrication of a novel MOS diode by indium incorporation control for microelectronic applications. J Semicond. 2017; 38 (6): 064004–064009p.

Nivetha S, Ayeshamariam A, Srinivasan MP, Punithavelan N, Perumalsamy R, Jayachandran M. Investigations of Doping of Sn with Ag2O as a Thin Film on Glass Plate for Morphological Studies. Iranian Journal of Science and Technology, Transactions A: Science. 2017; 1–12p.

AgO H, Tanaka I, Orofeo CM, Tsuji M, Ikeda KI. Patterned growth of graphene over epitaxial catalyst. Small. 2010; 6 (11): 1226–1233p.

Åhman J, Svensson G, Albertsson J. A reinvestigation of β-gallium oxide. Acta Crystallographica Section C: Crystal Structure Communications. 1996; 52 (6): 1336–1338p.

Víllora EG, Yamaga M, Inoue T, Yabasi S, Masui Y, Sugawara T, Fukuda T. Optical spectroscopy study on β-Ga2O3. Japanese journal of applied physics. 2002; 41 (6A): L622p.

Bordun OM, Kukharskii II, Dmitruk VV, Antonyuk VG, Savchin VP. Luminescence centers in α-Bi2O3 ceramics. Journal of Applied Spectroscopy. 2008; 75 (5): 681–684p.

Lovejoy TC, Chen R, Zheng X, Villora EG, Shimamura K, Yoshikawa H, Yamashita Y, Ueda S, Kobayashi K, Dunham ST, Ohuchi FS. Band bending and surface defects in β-Ga2O3. Applied Physics Letters. 2012; 100 (18): 181602p

Fowziya SA, Mohideen AM, Arasu MV, Jahangir AR, Saleem AM, Ayeshamariam A, Jayachandran M. Oxidative Hydrothermal Synthesis of Ce2O3–ZrO2–Y2O3 Nanocomposites and Their Photocatalytic and Biological Studies. Journal of Bionanoscience. 2018; 12 (4): 478–487p.

Long D, Li W, Ling L, Miyawaki J, Mochida I, Yoon SH. Preparation of nitrogen-doped graphene sheets by a combined chemical and hydrothermal reduction of graphene oxide. Langmuir. 2010; 26 (20): 16096–16102p.

Groot FMFD, Grioni M, Fuggle JC, Ghijsen J, Sawatzky GA, Petersen H. Oxygen 1s x-ray-absorption edges of transition-metal oxides. Physical Review B. 1989; 40 (8): 5715p.

Hu JQ, Deng B, Tang KB, Wang CR, Qian YT. Preparation and phase control of nanocrystalline silver indium sulfides via a hydrothermal route. Journal of Materials Research. 2001; 16 (12): 3411–3415p.

Salker AV, Desai MF. Low-temperature nitric oxide reduction over silver-substituted cobalt oxide spinels. Catalysis Science & Technology. 2016; 6 (2): 430–433p.

Iglesias-Silva E, Rivas J, Isidro LL, López-Quintela MA. Synthesis of silver-coated magnetite nanoparticles. Journal of Non-Crystalline Solids. 2007; 353 (8–10): 829–831p.

Korteweg GA. Determination of spin-Hamiltonian parameters from EPR powder spectra of Fe (HI) substituted in β-AgAlO2 and β-AgGaO2. Journal of Magnetic Resonance. 1969; 42 (2): 181–185p.

Kou JH, Gao J, Li ZS, Zou ZG. Research on photocatalytic degradation properties of organics with different new photocatalysts. Current Organic Chemistry. 2010; 14 (7): 728–744p.

Paola A, García-López E, Marcì G, Palmisano L. A survey of photocatalytic materials for environmental remediation. Journal of hazardous materials. 2012; 211: 3–29p.

Wang P, Huang B, Qin X, Zhang X, Dai Y, Wei J, Whangbo MH. Ag@ AgCl: a highly efficient and stable photocatalyst active under visible light. Angewandte Chemie International Edition. 2008; 47 (41): 7931–7933p.

Maruyama Y, Irie H, Hashimoto K. Visible light sensitive photocatalyst, delafossite structured α-AgGaO2. The Journal of Physical Chemistry B. 2006; 110 (46): 23274–23278p.

Zhu Q, Wang WS, Lin L, Gao GQ, Guo HL, Du H, Xu AW. Facile synthesis of the novel Ag3VO4/AgBr/Ag plasmonic photocatalyst with enhanced photocatalytic activity and stability. The Journal of Physical Chemistry C. 2013; 117 (11): 5894–5900p.

Ouyang S, Chen D, Wang D, Li Z, Ye J, Zou Z. From β-phase particle to α-phase hexagonal-platelet superstructure over AgGaO2: phase transformation, formation mechanism of morphology, and photocatalytic properties. Crystal Growth & Design. 2010; 10 (7): 2921–2927p.

Baba R, Nakabayashi S, Fujishima A, Honda K. Investigation of the mechanism of hydrogen evolution during photocatalytic water decomposition on metal-loaded semiconductor powders. The Journal of Physical Chemistry. 1985; 89 (10): 1902–1905p.


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